HYDROZIRCONIERUNG VON NITRILEN: DIE BILDUNG EIN- UND ZWEIKERNIGER (ALKYLIDENAMIDO)ZIRCONOCEN-KOMPLEXE

DOI: 10.1016/0022-328X(85)88111-0

Source and publish data:

Journal of Organometallic Chemistry p. 343 - 354 (1985)

Update date:2022-08-17

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Authors:

Froemberg, Wolfgang

Erker, Gerhard

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Article abstract of DOI:10.1016/0022-328X(85)88111-0

Cp2Zr(-N=CHR)Cl compounds (9a-9c: R=CH3, C6H5, CH2Ph, respectively) are formed upon hydrozirconation of nitriles.Subsequent reaction with an aryllithium reagent yields Cp2Zr(-N=CHR)Ar (14).The (alkylidene amido)zirconocene complexes are characterized by a

Full text of DOI:10.1016/0022-328X(85)88111-0

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