Journal of the Chemical Society, Dalton Transactions p. 1461 - 1464 (1983)
Update date:2022-08-10
Topics:
Arthers, Stephen A.
Beattie, Ian R.
Gomme, Robin A.
Jones, Peter J.
Odgen, J. Steven
The matrix i.r. and Raman spectra obtained from the vaporisation of potassium and caesium perrhenate show spectra characteristic of the molecular species MReO4 with C2ν symmetry.Additional 18O enrichment experiments provide an unequivocal assignment for the νrRe-O modes and it is also shown that the bond dipole model leads to a useful simulation of relative band intensities.
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Doi:10.1021/jp983468l
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