Tetrahedron Letters p. 3469 - 3472 (1994)
Update date:2022-08-11
Topics:
Vanhessche, Koen P. M.
Wang, Zhi-Min
Sharpless, K. Barry
The asymmetric dihydroxylation (AD) of primary allylic halides is described.Enantiomeric excesses range from 40 to 98percent.Subsequent base treatment gives epoxy alcohols in high yields.This strategy is further illustrated by the synthesis of (-)-diepoxybutane, an important C4-chiral building block.
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(1996)Doi:10.1016/j.tetlet.2009.03.212
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