Cascade Skeletal Rearrangement of Gold Carbene Intermediates: Synthesis of Medium-Sized Pyrimidine-Fused Benzolactones

DOI: 10.1002/adsc.202100572

Source and publish data:

Advanced Synthesis and Catalysis p. 3769 - 3774 (2021)

Update date:2022-08-29

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Authors:

Hu, Xiaoping

Liu, Yuanhong

Wang, Ali

Xie, Xin

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Article abstract of DOI:10.1002/adsc.202100572

A gold-catalyzed cyclization/cascade skeletal rearrangement of o-cyanophenylalkynones with 3-amino-benzo[d]-isoxazoles has been developed, which provides an approach for synthesizing medium-sized benzolactones. Based on the experimental results, we postul

Full text of DOI:10.1002/adsc.202100572

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