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Cyclopentindene (Benzopentalene): Generation by Flash Vacuum Pyrolysis and Subsequent Dimerisation

DOI: 10.1016/S0040-4039(00)73368-5

Source and publish data:

Tetrahedron Letters p. 4405 - 4408 (1994)

Update date:2022-08-11

Topics:

Authors:

Brown, Roger F. C.Brown, Roger F. C.

Choi, NeilChoi, Neil

Coulston, Karen J.Coulston, Karen J.

Eastwood, Frank W.Eastwood, Frank W.

Wiersum, Ulfert E.Wiersum, Ulfert E.

Jenneskens, Leonardus W.Jenneskens, Leonardus W.

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Article abstract of DOI:10.1016/S0040-4039(00)73368-5

Cyclopentindene (benzopentalene, 7) is generated by flash vacuum pyrolysis of 3-phenylphthalic anhydride (6), biphenylene (3) or diphenic anhydride (4).It dimerises readily and adds cyclopentadiene above -70 deg C, but it does not equilibrate at 900 deg C with as-indacene (1).

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Full text of DOI:10.1016/S0040-4039(00)73368-5

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Product name:BENZENE, [3H]- 3-20 MCI(111-740 MBQ)/MMOL, DELIVERED >= 96% PURE WITH HPLC RADIOCHROMATOGRAM

Cas No:13967-78-7

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