Phenyl vinyl thioether: A convenient source of the ethylene 1,1-dianion

DOI: 10.1016/S0040-4039(99)01731-1

Source and publish data:

Tetrahedron Letters p. 8173 - 8176 (1999)

Update date:2022-08-18

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Authors:

Foubelo, Francisco

Gutierrez, Ana

Yus, Miguel

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Article abstract of DOI:10.1016/S0040-4039(99)01731-1

The successive reaction of phenyl vinyl thioether (1) with n-butyllithium and an electrophile [E₁= PhCHO, (CH₂)₄CO, (CH₂)₅CO] in THF at -78°C gives, after hydrolysis, the expected methylenic hydroxy t

Full text of DOI:10.1016/S0040-4039(99)01731-1

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