Thallium ion mediated ring expansion of 1-trimethylsilyloxy-1- alkenylcycloalkanes to α-exo-methylenecycloalkanones

DOI: 10.1016/0040-4039(96)00701-0

Source and publish data:

Tetrahedron Letters p. 3865 - 3866 (1996)

Update date:2022-08-10

Topics:

Authors:

Kim Kim

Kee Han Uh

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Article abstract of DOI:10.1016/0040-4039(96)00701-0

Treatment of TMS ethers of 1-alkenyl-1-cycloalkanols with thallium trifluoro acetate in acetonitrile affords the ring expanded α-exo- methylenecycloalkanones.

Full text of DOI:10.1016/0040-4039(96)00701-0

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