Journal of the Chemical Society. Chemical communications p. 714 - 715 (1990)
Update date:2022-08-16
Topics:
Hay, Robert W.
Govan, Norman
A lanthanum macrocycle is shown to be an effective catalyst for the hydrolysis of the phosphate triester 2,4-dinitrophenyl diethyl phosphate, at pH 9 the rate enhancement using 2.5*1E-3 mol dm-3 catalyst at 25 deg C being ca. 1E3-fold; the reaction is shown to be catalytic rather than stoicheiometric, and possible mechanisms are considered to account for the catalysis.
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