Stereoselective electrochemical synthesis of silyl enol ethers using a sacrificial magnesium anode

DOI: 10.1016/0022-328X(94)05368-L

Source and publish data:

Journal of Organometallic Chemistry p. 27 - 32 (1995)

Update date:2022-08-30

Topics:

Authors:

Bonafoux, Dominique

Bordeau, Michel

Biran, Claude

Dunogues, Jacques

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Article abstract of DOI:10.1016/0022-328X(94)05368-L

The 2-pyrrolidone magnesium salt electrogenerated in an undivided cell fitted with a sacrificial magnesium anode allowed the stereoselective synthesis of Z-silyl enol ethers upon deprotonation of enolizable ketones in the presence of a complexing agent. Keywords: Silyl enol ethers; Stereoselective synthesis; Electrogenerated bases; Sacrificial magnesium anode

Full text of DOI:10.1016/0022-328X(94)05368-L

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