Conversion of 2-alkenylcyclopropylcarbenechromium complexes to 5-alkenyl-2-cyclopentenones: A stereospecific three- To fivecarbon ring expansion reaction

DOI: 10.1016/0040-4039(95)01124-Z

Source and publish data:

Tetrahedron Letters p. 5687 - 5690 (1995)

Update date:2022-08-11

Topics:

Authors:

Herndon, James W.

Hill, David K.

McMullen, Leonard A.

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Article abstract of DOI:10.1016/0040-4039(95)01124-Z

Upon thermolysis, 2-alkenylcyclopropylcarbene-chromium complexes are converted to 5-alkenyl-2-cyclopentenones. The reaction appears to proceed with retention of configuration in the absence of steric factors.

Full text of DOI:10.1016/0040-4039(95)01124-Z

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