A Superior Synthesis of -Methanofullerenes: The Reaction of Sulfonium Ylides with C60

DOI: 10.1016/0040-4039(95)01443-L

Source and publish data:

Tetrahedron Letters p. 6843 - 6846 (1995)

Update date:2022-08-11

Topics:

Authors:

Wang, Yihan

Cao, Jingrong

Schuster, David I.

Wilson, Stephen R.

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Article abstract of DOI:10.1016/0040-4039(95)01443-L

The addition-elimination reaction of stabilized sulfonium ylides 1a-f to C60 provides a new high yield route to <6,6>-methanofullerenes.The rates of reaction differ with the nucleophilicity of the ylides.

Full text of DOI:10.1016/0040-4039(95)01443-L

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