Synthesis and electrical properties of crosslinked poly(1,2,4,5-phenylenedivinylene) and copolymers

Article abstract of DOI:10.1080/10587259408039187

Crosslinked conjugated conducting polymer, poly(1,2,4,5-penylene divinylene)(PPDV) and its copolymers were prepared by the water-soluble precursor method. The spectral characteristics of these materials have been investigated by using UV-visible and FT-IR spectroscopy. PPDV hemopolymer film could not be stretched due to its crosslinked structure, so this homopolymer could slightly be duped with strong oxidant, FeCl₃, to produce a very low conductivity value of 3×10^-6 Scm^-1. However, copolymers containing PDV units and DMPV units showed considerably high conductivities ranging from 3×10^-2 to 68 Scm^-1, when doped with FeCl₃, depending upon the copolymer composition.

Full text of DOI:10.1080/10587259408039187

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Molecular Crystals and Liquid Crystals
Science and Technology. Section A.
Molecular Crystals and Liquid Crystals
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Synthesis and Electrical Properties
of Crosslinked Poly(1,2,4,5-
Phenylenedivinylene) and Copolymers
Hong-Ku Shim a & Hyeong-Gon Noh a
a Department of Chemistry , Korea Advanced Institute of Science
and Technology Taejon , Korea , 305-701
Published online: 04 Oct 2006.
To cite this article: Hong-Ku Shim & Hyeong-Gon Noh (1994) Synthesis and Electrical Properties
of Crosslinked Poly(1,2,4,5-Phenylenedivinylene) and Copolymers, Molecular Crystals and Liquid
Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 247:1, 23-30,
DOI: 10.1080/10587259408039187
To link to this article: http://dx.doi.org/10.1080/10587259408039187
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