Generation of phosphide anions from phosphorus red and phosphine in strongly basic systems to form organylphosphines and -oxides

Article abstract of DOI:10.1080/10426509608545225

Generation of phosphide anions from phosphorus red or phosphine under the action of strong bases followed by their reactions with organyl halides, electrophilic alkenes and alkynes proves to be the most straightforward and well-controlled route to mono-, di-or triorganylphosphines or phosphine oxides of diverse structure.

Full text of DOI:10.1080/10426509608545225

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Phosphorus, Sulfur, and Silicon and
the Related Elements
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Generation of Phosphide
Anions from Phosphorus Red
and Phosphine in Strongly
Basic Systems to Form
Organylphosphines and -Oxides
Boris Trofimov , Nina Gusarova & Lambert Brandsma
a Institute of Organic Chemistry, Siberian Branch, Russian
Academy of Sciences , 1, Favorsky Street, 664033 Irkutsk,
Russia
b Institute of Organic Chemistry, Siberian Branch, Russian
Academy of Sciences , 1, Favorsky Street, 664033 Irkutsk,
Russia
c Department of Preparative Organic Chemistry ,
University of Utrecht , Padualaan 8, 3584 CH Utrecht, The
Netherlands
Published online: 06 Aug 2008.
To cite this article: Boris Trofimov , Nina Gusarova & Lambert Brandsma (1996) Generation
of Phosphide Anions from Phosphorus Red and Phosphine in Strongly Basic Systems to Form
Organylphosphines and -Oxides, Phosphorus, Sulfur, and Silicon and the Related Elements,
109:1-4, 601-604, DOI: 10.1080/10426509608545225
To link to this article: http://dx.doi.org/10.1080/10426509608545225
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