Synthesis, structure, and reactions of the first rotational Isomers of stable thiobenzaldehydes, 2,4,6-tris[bis(trimethylsilyl)methyl]thiobenzaldehydes

DOI: 10.1002/chem.19970030111

Source and publish data:

Chemistry - A European Journal p. 62 - 69 (1997)

Update date:2022-07-30

Topics:

Authors:

Takeda, Nobuhiro

Tokitoh, Norihiro

Okazaki, Renji

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Article abstract of DOI:10.1002/chem.19970030111

The first rotational isomers of thiobenzaldehydes, TbtCH=S (2a and 2b; Tbt = 2,4,6-tris[bis(trimethylsilyl)methyl]phenyl), were synthesized and isolated as stable crystalline compounds by the desulfurization of the corresponding overcrowded cyclic polysul

Full text of DOI:10.1002/chem.19970030111

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