Journal of the Chemical Society - Faraday Transactions p. 477 - 482 (1992)
Update date:2022-08-17
Topics:
Sheng, Tai-Cheng
Rebenstorf, Bernd
Wideloev, Anders
Larsson, Ragnar
The pyrolysis of Fe-tetraphenylporphyrin chloride (FeClTPP) has been examined by FTIR spectroscopy.Two series of samples, with and without additional carbon black, were studied.It was found that the decomposition of FeClTPP occured in a very narrow range of temperature.The mixture of FeClTPP and carbon decomposed at a lower temperature than pure crystalline FeClTPP.The oxygen chemically adsorbed on the surface of carbon black may play an important role in this respect.The mechanism of pyrolysis have been discussed and a model of three steps of decomposition was proposed.The first step has been followed also by measuring the chlorine content by means of quantitative XPS.
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