Collection of Czechoslovak Chemical Communications p. 1682 - 1690 (2001)
Update date:2022-08-11
Topics:
Svatos, Ales
Kalinova, Blanka
Kindl, Jiri
Kuldova, Jelena
Hovorka, Oldrich
Do Nascimento, Ruth Rufino
Oldham, Neil J.
(9Z,11E)-Hexadeca-9,11-dienal (1) was identified as a major component of the sex pheromone of the sugarcane borer Diatraea saccharalis. The identification is based on mass spectral examination of the extracts prepared from calling females, derivatization experiments with 4-methyl-3,5-dihydro-1,2,4-triazole-3,5-dione (2), stereospecific synthesis of dienal 1, and gas chromatography (GC) with electroantennographic detection (GC-EAD). In GC analysis, the antennaly active component and synthetic dienal 1 show identical retention times on several GC phases. However, the behavioral activity of synthetic 1 was much weaker than that of natural extracts. This suggests that an additional component(s) might be involved in sexual communication of this species.
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