Directed aminomethylation of 3-hydroxy-2(1H)-pyridinones and 3-hydroxy-4(1H)-pyridinones: Synthesis of iso-deferiprone

DOI: 10.1016/0040-4020(95)01016-5

Source and publish data:

Tetrahedron p. 1835 - 1840 (1996)

Update date:2022-08-10

Topics:

Authors:

Patel, Manojbhai K.

Raymond, Fox

Taylor, Paul D.

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Article abstract of DOI:10.1016/0040-4020(95)01016-5

The site of aminomethylation of N-unsubstituted 3-hydroxy-2-(1H)-pyridinones and 3-hydroxy-4(1H)-pyridinones, under Mannich reaction conditions, is directed by the hydroxyl group when this is unprotected and by the keto group when the hydroxyl is protecte

Full text of DOI:10.1016/0040-4020(95)01016-5

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Product name:2-methyl-3-benzyloxy-5-(N,N-dimethyl)aminomethyl-pyridin-4-one

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