Tetrahedron p. 10871 - 10882 (1997)
Update date:2022-08-17
Topics:
De Riccardis, Francesco
Izzo, Irene
Di Filippo, Marcello
Sodano, Guido
D'Acquisto, Fulvio
Carnuccio, Rosa
Synthesis of cytotoxic steroidal derivatives containing a quinone moiety is described. The synthetic strategy is based on an unusual A + CD → ABCD Diels-Alder approach which generates 9β-H cholestane analogs. The adducts formed are efficiently aromatized
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