Journal of the American Chemical Society p. 3961 - 3966 (1983)
Update date:2022-08-30
Topics:
McGarrity
Cox
Phillip
Protonation on both terminals of diazomethane can be observed only under conditions of kinetic control in extremely acidic solutions, when the acidity is reduced only the thermodynamically more stable C-protonated isomer can be seen. Loss of nitrogen from the methanediazonium ion is nucleophile assisted in the very highly acidic medium of HOSO//2F/SbF//5/SO//2ClF.
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