Tetrahedron p. 1003 - 1007 (1982)
Update date:2022-08-10
Topics:
Yadav, J. S.
Patil, Dilip G.
Krishna, R. R.
Chawla, H. P. S.
Dev, Sukh
Heterolytic fragmentation of homoallylic alcohols incorporated in a bicyclo<2,2,1>heptane system with electrophilic reagents or that of the corresponding epoxides with acids, is described.A short route, via this fragmentation, to synthon 25, potentially useful in the syntheses of cis-jasamone and prostanoids, is reported.
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Doi:10.1002/bio.3446
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