Berichte der Bunsengesellschaft/Physical Chemistry Chemical Physics p. 24 - 30 (1987)
Update date:2022-08-17
Topics:
Dall'O
Heydtmann
The photolysis of ketene at 313 nm was studied in the presence of fluoroethene and oxygen. The product formation was observed as a function of total pressure between 12 and 1080 mbar. Chemically activated fluorocyclopropane was formed by addition of singlet methylene to the double bond, and subsequent isomerization to the fluoropropenes as well as decomposition of these primary products to allene, propyne and HF was observed. The product yield was described by RRKM calculations; a stepladder deactivation model was used.
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