Bulletin of the Chemical Society of Japan p. 953 - 960 (1988)
Update date:2022-08-17
Topics:
Yui, Koji
Aso, Yoshio
Otsubo, Tetsuo
Ogura, Fumio
In order to discover new electron donors for conducting charge-transfer complexes, the four title compounds 1-4 composed of two heterocycles have been prepared via 1,8-dichalcogen-bridged naphthalene.The cyclic voltammetery indicates that symmetrical 1 and 2 are poor donors, but unsymmetrical 3 and 4 possess considerable donor abilities.The latter compounds are thus capable of forming some crystalline charge-transfer complexes with strong acceptors such as TCNQ, TCNQF4, and DDQ, which are, however, semi-conducting.
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