Highly Selective Cobalt-Catalyzed Hydrovinylation of Styrene
FULL PAPERS
cell. 379 parameters were refined with no restraints. R1/wR2
[I>2s(I)]: 0.0389/0.1171. R1/wR2 [all refl.]: 0.0537/0.1229.
S=1.157. Residual electron density between À0.41 and
0.38 eꢄ3.
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Co(7)Cl2: C39H32Cl2CoOP2, MW=708.42gmolÀ1, blue
plates, 0.30ꢅ0.30ꢅ0.09mm3, monoclinic, P21/c (no. 14), a=
16.9077(1),
b=10.5145(1),
c=40.3113(3) ꢄ,
b=
111.2220(3)8, V=6680.39(9) ꢄ3, Z=8, Dx =1.409gcmÀ3, m=
0.801mmÀ1. 56974 reflections were measured up to a resolu-
tion of (sin q/l)max =0.62 ꢄÀ1. The reflections were corrected
for absorption using the routine DELABS of the program
PLATON[31] (0.62–0.93 correction range). 13107 reflections
were unique (Rint =0.0435) and 9535 reflections were ob-
served [I>2s(I)]. 811 parameters were refined with no re-
straints. R1/wR2 [I>2s(I)]: 0.0339/0.0728. R1/wR2 [all
refl.]: 0.0583/0.0832. S=1.032. Residual electron density be-
tween À0.38 and 0.37 eꢄ3. CCDC 701657 [compound
Co(6)Cl2] and CCDC 701658 [compound Co(7)Cl2] contain
the supplementary crystallographic data for this paper.
These data can be obtained free of charge from The Cam-
c.uk/data_request/cif
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Acknowledgements
We thank Eindhoven University of Technology, the National
Research School Combination on Catalysis (NRSC-C) and
The Netherlands Organization for Scientific Research
(NWO-CW) for financial support. Funding by the EC
(HPRN-CT-2001-00187, AC3S) is kindly acknowledged.
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