Stereoselective Formation of E- or Z-Exocyclic Alkenes via Radical Cyclization Reactions oof Acetylenic Esters

DOI: 10.1021/jo00049a008

Source and publish data:

Journal of Organic Chemistry p. 6099 - 6101 (1992)

Update date:2022-08-16

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Authors:

Lowinger, Timothy B.

Weiler, Larry

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Article abstract of DOI:10.1021/jo00049a008

The intramolecular cyclization of secondary alkyl radicals with α,β-alkynyl esters proceeds stereoselectively to give either E- or Z-exocyclic alkenes, depending upon the reaction conditions.

Full text of DOI:10.1021/jo00049a008

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