Some preparation methods of a tricyclo[4.1.0.02,7]hept-4-en-3-one skeleton

Article abstract of DOI:10.1080/00397919508015880

β-Elimination of acetic acid was elaborated in our synthetic method of a tricyclo[4.1.0.0^2,7]hept-4-en-3-one (tropovalene) skeleton. Presented was a new synthetic method of this skeleton, which consists of a reaction sequence of 1,4-addition of propanethiol to bicyclo[3.2.0]hepta-3,6-dien-2-one, photochemical construction of bicyclobutane skeleton, oxidation, and thermal elimination of sulfenic acid.

Full text of DOI:10.1080/00397919508015880

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Synthetic Communications: An
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Some Preparation Methods of
a Tricyclo[4.1.0.02,7]Hept-4-
En-3-One Skeleton
Shigeharu Wakabayashi a , Naoki Saito b , Yoshikazu
Sugihara a b , Takashi Sugimura b & Ichiro Murata b
a Department of Chemistry, Suzuka University of
Medical Science and Technology, Kishioka-cho,
Suzuka, Mie, 510-02, Japan
b Department of Chemistry, Faculty of Science,
Osaka University, Toyonaka, Osaka, 560, Japan
Version of record first published: 23 Sep 2006.
To cite this article: Shigeharu Wakabayashi, Naoki Saito, Yoshikazu Sugihara,
Takashi Sugimura & Ichiro Murata (1995): Some Preparation Methods of a
Tricyclo[4.1.0.02,7]Hept-4-En-3-One Skeleton, Synthetic Communications: An
International Journal for Rapid Communication of Synthetic Organic Chemistry, 25:13,
2019-2027
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