Total synthesis and morphogenesis-inducing activity of (±)-thallusin and its analogues

DOI: 10.1016/j.tetlet.2007.04.075

Source and publish data:

Tetrahedron Letters p. 4229 - 4233 (2007)

Update date:2022-08-11

Topics:

Authors:

Nishizawa, Mugio

Iyenaga, Tomoaki

Kurisaki, Takahiro

Yamamoto, Hirofumi

Sharfuddin, Mohammed

Namba, Kosuke

Imagawa, Hiroshi

Shizuri, Yoshikazu

Matsuo, Yoshihide

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Article abstract of DOI:10.1016/j.tetlet.2007.04.075

Total synthesis of (±)-thallusin was achieved using Hg(OTf)₂·PhNMe₂-induced olefin cyclization, and Suzuki coupling with a pyridylboronic acid derivative. Hg(OTf)₂ also acted as a catalyst to isomerize the double bond into

Full text of DOI:10.1016/j.tetlet.2007.04.075

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