Journal of the Chemical Society. Chemical communications p. 1758 - 1760 (1992)
Update date:2022-08-11
Topics:
Rockcliffe, David A.
Martell, Artur E.
The stoichiometric oxidations of hydroquinones, phenols, 3,5-di-tert-butylcatechol and 3,4-dimethylaniline with a macrocyclic Cu(I) dioxygen complex and with a Cu(II) complex show that in some cases the substrate is oxidized both by the Cu(I) dioxygen complex and by the corresponding Cu(II) complex, while in other cases the Cu(II) complex shows no activity; the combination of the Cu(I) dioxygen complex and the Cu(II) complex as oxidants results in catalytic oxidation of the substrate, but no catalysis is observed when only the Cu(I) dioxygen complex is active.
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