Bulletin of the Chemical Society of Japan p. 3030 - 3033 (1993)
Update date:2022-08-10
Topics:
Watanabe, Yoshihiko
Yoneda, Tetsuo
Okumura, Tatsuya
Ueno, Yoshio
Toru, Takeshi
Free radical allylations of α-seleno carbonyl compounds with tributyl-substituted 2,4-pentadienyltin, 2-methyl-2-propenyltin, 2-butenyltin, and 3-methyl-2-butenyltin, are described. Such successful C-C bond formations, in particular with the 2-butenyltin and the 3-methyl-2-butenyltin, are owing to the high reactivity of the α-carbon radical, generated from α-seleno carbonyl compounds, toward allylic tin compounds.
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