HIGHLY REACTIVE METALS FROM POTASSIUM-GRAPHITE. PREPARATION AND USE OF TITANIUM-GRAPHITE AND TIN-GRAPHITE

DOI: 10.1016/0022-328X(85)88107-9

Source and publish data:

Journal of Organometallic Chemistry p. 307 - 312 (1985)

Update date:2022-08-17

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Authors:

Boldrini, Gian Paolo

Savoia, Diego

Tagliavini, Emilio

Trombini, Claudio

Umani-Ronchi, Achille

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Article abstract of DOI:10.1016/0022-328X(85)88107-9

The potassium-graphite route to active forms of metals has been extended to the preparation of titanium-graphite (Ti-Gr) and tin-graphite (Sn-Gr).The Ti-Gr is used to achieve the reductive coupling of ketones to give alkenes, and Sn-Gr is used in the preparation of diallyltin dibromide complexes which react with aldehydes to give homoallylic alcohols.

Full text of DOI:10.1016/0022-328X(85)88107-9

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