Russian Journal of Organic Chemistry p. 1313 - 1317 (2011)
Update date:2022-08-11
Topics:
Golubev
Sen
Autoreduction of bis(4-methoxyphenyl)oxoammonium perchlorate in aqueous alkali follows a mechanism different from that generally accepted for diaryloxoammonium salts. Bis(4-methoxyphenyl)-oxoammonium cation undergoes hydrolysis to the corresponding quinone imine oxide and methanol, the latter gives rise to methoxide ion which reduces the oxoammonium cation to intermediate bis(4-methoxyphenyl)-hydroxylamine. The reaction of bis(4-methoxyphenyl) hydroxylamine with the initial cation yields bis-(4-methoxyphenyl)nitroxyl, and the quinone imine oxide undergoes disproportionation to N-(4-methoxyphenyl)-1,4- benzoquinone imine and oxidation products. Pleiades Publishing, Ltd., 2011.
View MoreChangzhou Hopschain Chemical Co.,Ltd
Contact:86-519-85528066
Address:Room 710, Unit A, Xingbei Development Mansion, Tongjiang Road, Changzhou City,213000, China
Naturalin Bio-Resource Co., Ltd
website:http://www.naturalin.com
Contact:+86-0731-84430651
Address:B1-402, Lu-Valley Enterprise Square.No.27 Wenxuan Road. Lu-Valley Hi-Tech District.
SHIJIAZHUANG HENRYTE CHEMICALS CO,.LTD
Contact:+86-311-85208698 311-80837698
Address:NO.166, yuhua west road, SHIJIAZHUANG, China
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD
website:http://www.czyys.com
Contact:0086-519-88802789
Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China
Nanjing Yuance Industry&Trade Co., Ltd.
website:http://www.njyuance.cn/
Contact:+86-25-85439097
Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
Doi:10.1039/tf9646000700
(1964)Doi:10.1021/ja00271a011
(1986)Doi:10.1016/j.molcatb.2015.11.013
(2016)Doi:10.1063/1.3585126
(2011)Doi:10.1055/s-0037-1612413
(2019)Doi:10.1021/acs.orglett.9b00988
(2019)