Chemistry Letters p. 1121 - 1124 (1988)
Update date:2022-08-29
Topics:
Komiyama, Makoto
Regioselective cleavage (selectivity 98percent) of the P-O(2') bond of cytidine 2',3'-cyclic monophosphate is carried out at pH 11.08, 20 deg C by use of α-cylodextrin as catalyst.Without α-cyclodextrin, the selectivity is only 47percent due to concurrent cleavage of the P-O(3') bond.The regioselective catalysis is ascribed to the formation of a complex between α-cyclodextrin and the monophosphate.
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