Face selection in additions to the trigonal C2 site in quaternized 5-azaadamantane derivatives

DOI: 10.1021/ja00151a005

Source and publish data:

Journal of the American Chemical Society p. 11421 - 11425 (1995)

Update date:2022-08-30

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Authors:

Lau, Jacqueline

Gonikberg, Elena M.

Hung, Jui-Te

Le Noble, William J.

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Article abstract of DOI:10.1021/ja00151a005

The quaternary N-allyl bromide salt 5 of allyl α-[2-(5-azaadamantylidene)]benzyl ether upon warming gave the Claisen rearrangement products 6 is the ratio E/Z = 93:7. The epoxidation of the N-oxide 8 of 2-methylene-5-azaadamantane 7 with m-CPBA gives rise

Full text of DOI:10.1021/ja00151a005

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