
Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1547 - 1550 (1992)
Update date:2022-08-11
Topics:
Gitis, K. M.
Raevskaya, N. I.
Zaitsev, A. V.
Borovkov, V. Yu.
Kozan, S. B.
Isagulyants, G. V.
An investigation has been conducted into the effect of the acid and dehydrogenating functions of an aluminoplatinum catalyst on the synthesis of 2-methylimidazole from ethylenediamine and acetic acid.It has been established that formation of the intermediate 2-methylimidazoline involves the acid Al2O3 centers and its rate of formation is greater than the rate of its subsequent dehydrogenation to 2-methylimidazole on the Pt centers.The symbatic nature of the variations in the 2-methylimidazole yield and the surface area of the platinum in the aluminoplatinum catalyst has been demonstrated.Keywords: C-alkylimidazoles, 2-methylimidazole, aluminoplatinum catalyst.
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