Tetrahedron Letters p. 4791 - 4794 (1980)
Update date:2022-08-25
Topics:
Mesch, Keith A.
Quin, Louis D.
Syn-Substituted phosphines of the 7-phosphanorbornene system form unstable phosphorane adducts with methanol that either fragment by retro-McCormick cycloaddition or undergo polytopal rearrangement and loss of methanol to give the first example of anti phosphines.
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