Journal of Organic Chemistry p. 549 - 550 (1980)
Update date:2022-08-10
Topics:
Campbell, James B.
Brown, Herbert C.
Sodium methoxyalkenyldialkylborates, obtained in the simple treatment of alkenyldialkylboranes with sodium methoxide, react readily with cuprous bromide-methyl sulfide at 0 deg C to afford symmetrical conjugated dienes.The dienes are formed with retention of configuration predetermined from the stereochemistry of the initial alkenylborane intermediate.
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