European Journal of Organic Chemistry p. 1884 - 1888 (2017)
Update date:2022-08-11
Topics:
Zhang, Xinghua
Shi, Zheng
Shao, Changwei
Zhao, Jinlong
Wang, Dungai
Zhang, Gaoqi
Li, Liang
A one-pot, three-component coupling reaction of primary alkyl halides (or tosylates), elemental sulfur/selenium, and P(O)–H compounds in water was developed. This procedure affords valuable phosphorothioates/phosphoroselenoates, including P-chiral compounds, with broad substrate scope and high efficiency. Moreover, this facile protocol can be applied to gram-scale preparations.
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