Tetrahedron Letters p. 6225 - 6228 (1994)
Update date:2022-08-30
Topics:
Dolbier Jr., William R.
Rong, Xiao X.
A Hammett study of hydrogen atom abstraction by the perfluoro-n-heptyl radical is presented. Excellent correlation of the rates with σ+, with a ρ+ value of -0.56, provides important corroboration of the substantial influence of transition state polar effects on this unexpectedly slow process.
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