Tetrahedron Letters p. 3159 - 3162 (1980)
Update date:2022-08-31
Topics:
Venier, Clifford G.
Wing, Feagin A. Jr.
Barager, Howard J.
Phenylsulfinyl carbenium ion, generated by the acid-catalyzed decomposition of phenyl diazomethyl sulfoxide or the silver-assisted solvolysis of phenyl iodomethyl sulfoxide, is trapped by hydroxylic solvents to yield phenyl methyl sulfone.The possibility of the intermediacy of either phenylsulfinyl carbene or phenylsulfinylmethyl acetate has been ruled out.
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(1962)
