Heterocycles p. 1439 - 1445 (2005)
Update date:2022-08-30
Topics:
Alici, Buelent
Oezdemir, Ismail
Guerbuez, Nevin
Cetinkaya, Engin
Cetinkaya, Bekir
Four functionalized bis(1,4,5,6-tetrahyropyrimidinium) salts (2a-d) have been prepared and characterized by conventional spectroscopic methods and elemental analyses. A highly effective, easy to handle and environmentally benign process for palladium mediated Suzuki cross-coupling was developed. The in situ prepared three component system Pd(OAc)2 / bis(1,4,5,6-tetrahyropyrimidinium) bromides (2a-d) and Cs2CO 3 catalyses quantitatively the Suzuki cross-coupling of deactivated aryl chloride.
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