Journal of Fluorine Chemistry p. 113 - 120 (1995)
Update date:2022-08-16
Topics:
Chen, Grace J.
Chen, Loomis S.
The (perfluoroalkyl)- and (perfluorooxaalkyl)diazines, 2,4-bis(perfluorooctyl)pyrimidine (3), 2,4,6-tris(perfluorooctyl)pyrimidine (6a), 2,4,6-tris(perfluoro-6-methyl-5-oxaheptyl)pyrimidine (6b), 3,6-bis(perfluorooctyl)pyridazine (10) and 2,6-bis(perfluorooctyl)pyrazine (13), have been prepared in good yield.This was accomplished by using chloro-substituted diazines as substrates in copper mediated cross-coupling reactions with perfluoroalkyl and perfluorooxaalkyl iodides.The yields of the cross-coupled products are influenced by the reaction conditions as well as by the structure of the fluoroaliphatic iodides and substrates. - Keywords: Perfluoroalkylations; Perfluorooxaalkylations; Chloro-substituted diazines; Cross-coupling; NMR spectroscopy; Mass spectrometry
View MoreNINGBO PANGS CHEM INT’L CO., LTD.
Contact:+86-0574-27666801
Address:Floor 21, Building 11, Xintiandi, No. 689, Shijiroad, Ningbo, Zhejiang, China
Jinan Boss Chemical Industry Co., Ltd.
website:http://www.chemboss.com.cn
Contact:+86-531-58591595
Address:No2.Hualong Road, Jinan, China
shanghai jinshan pharmaceutical Co.,Ltd
Contact:021-57363011,13681638167
Address:No. 7966 Tingfeng Road,Jinshan,Shanghai,China
Tianjin Anda North Industrial & Business Co.Ltd.
Contact:86-22-24999306
Address:No.11 Erwei Road,Dongli Development Area,Tianjin,China
Contact:+86-13666670345
Address:Agricultural Development Zone, Haining, Jiaxing, Zhejiang
Doi:10.1002/hlca.19830660720
(1983)Doi:10.1002/recl.19951140303
(1995)Doi:10.1039/jr9410000145
(1941)Doi:10.1002/bkcs.12201
(2021)Doi:10.1016/j.jcat.2012.05.009
(2012)Doi:10.1021/ja00455a013
(1977)