IDENTIFICATION OF THE PHENYLCYCLOHEXADIENYL RADICAL IN THE IRRADIATED BENZENE CRYSTAL.

Article abstract of DOI:10.1080/00268948008071421

In an irradiated benzene crystal, new absorption lines were observed on the low energy side in addition to the usual lines due to the cyclohexadienyl radical. These lines were attributed to the phenylcyclohexadienyl radical arising from the addition of the phenyl radical to a benzene molecule in the solid lattice. The isolated radical is quite stable for laser fluorescence and excitation studies. The deuterium shifts of the lowest electronic transition for a number of the cyclohexadienyl radicals are presented. A method of using the magnitude of the deuterium shift to estimate the size of the radical is proposed.

Full text of DOI:10.1080/00268948008071421

Molecular Crystals and Liquid Crystals
ISSN: 0026-8941 (Print) (Online) Journal homepage: http://www.tandfonline.com/loi/gmcl16
Identification of the Phenylcyclohexadienyl Radical
in the Irradiated Benzene Crystal
T. Nakayama & S. J. Sheng
To cite this article: T. Nakayama & S. J. Sheng (1980) Identification of the
Phenylcyclohexadienyl Radical in the Irradiated Benzene Crystal, Molecular Crystals and Liquid
Crystals, 59:3-4, 175-180, DOI: 10.1080/00268948008071421
To link to this article: http://dx.doi.org/10.1080/00268948008071421
Published online: 20 Apr 2011.
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Date: 05 June 2016, At: 08:48