Selective intramolecular cleavage of the carbon-silicon bond by palladium salts

DOI: 10.1016/0022-328X(94)87166-3

Source and publish data:

Journal of Organometallic Chemistry p. 213 - 216 (1994)

Update date:2022-08-11

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Authors:

Valk, Jean-Marc

Boersma, Jaap

Koten, Gerard van

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Article abstract of DOI:10.1016/0022-328X(94)87166-3

Several (aryl)trimethylsilane derivatives containing a potentially intramolecularly coordinating dimethylaminomethyl group were prepared and treated with Li2PdCl4 or Pd(OAc)2.Highly selective cleavage of the aryl-C-Si bond took place to give the correspon

Full text of DOI:10.1016/0022-328X(94)87166-3

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