Chemistry Letters p. 611 - 612 (1985)
Update date:2022-08-11
Topics:
Hiyama, Tamejiro
Sawahata, Miwa
Kusano, Yukari
Allyl addition to enolizable aldehyde and ketones is achieved efficiently with manganese reagents generated by the reaction of allyl bromide with MnCl2-LiAlH4 or Mn powder.The Wacker oxidation of the β-tetralone adducts gives an acetonyl moiety typical to an anti-tumor antibiotic, feudomycin.
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(1970)
