Drastic Effects of Dioxygen on the Selectivity of Reduction by LiAlH4. Milder Conditions Made Possible by Strictly Anaerobic Conditions

DOI: 10.1016/0040-4039(95)01291-O

Source and publish data:

Tetrahedron Letters p. 6457 - 6460 (1995)

Update date:2022-08-16

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Authors:

Peralez, Eric

Negrel, Jean-Claude

Chanon, Michel

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Article abstract of DOI:10.1016/0040-4039(95)01291-O

Reduction of the gem-disubstituted cyclopropane 1 with LiAlH4 yields different results under strictly anaerobic conditions and loosely anaerobic ones.Under strictly anaerobic conditions, (+)-1-bromo-2,2-diphenylcyclopropanecarbinol 2 is quantitatively red

Full text of DOI:10.1016/0040-4039(95)01291-O

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