Preparation, NMR spectra and reactivity of pentafluorophenyltetrafluorosilicates M+-

DOI: 10.1016/0022-328X(95)05616-W

Source and publish data:

Journal of Organometallic Chemistry p. 155 - 160 (1995)

Update date:2022-08-03

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Authors:

Frohn, H. J.

Bardin, V. V.

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Article abstract of DOI:10.1016/0022-328X(95)05616-W

Pentafluorophenyltetrafluorosilicates M⁺ ^- were obtained from pentafluorophenyltrifluorosilane C6F5SiF3 and ionic fluorides MF (M=K, Cs, Me4N) in anhydrous MeCN or diglyme.The reactivity of M⁺ ^- toward electrophiles was studied.Keywords: Pentafluorophenyl; Fluorosilicate anion; Desilylation

Full text of DOI:10.1016/0022-328X(95)05616-W

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