Journal of the American Chemical Society
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might lead to the generation of macromolecular motors.23a,b
Finally, the possibility to perform dynamic covalent chemis-
try along the C=N-bond (in this special ADMET-case also by
inducing dynamic metathesis32) allows for the generation of
imine-based dynamers6,33 capable of executing three types of
dynamic operations, i.e. in response to light, metal ions and
constitution.
Chichester, UK; b) Lehn, J.-M. Angew. Chem. Int. Ed. 2015, 54, 3276;
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in press.
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S.; Eivgi, O.; Berkovich, I.; Lemcoff, N. G. Chem. Rev. 2015, DOI:
10.1021/acs.chemrev.5b00290.
ASSOCIATED CONTENT
Supporting Information
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a) Bertin, P. A.; Gibbs, J. M.; Shen, C. K.-F.; Thaxton, C. S.;
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All experimental and analytical data. This material is availa-
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Pomposo, J. A. Polym. Int. 2014, 63, 589.
a) Terashima, T.; Mes, T.; De Greef, T. F. A.; Gillissen, M.
AUTHOR INFORMATION
A. J.; Besenius, P.; Palmans, A. R. A.; Meijer, E. W. J. Am. Chem. Soc.
2011, 133, 4742; b) Huerta, E.; Stals, P. J. M.; Meijer, E. W.;
Palmans, A. R. A. Angew. Chem. Int. Ed. 2013, 52, 2906.
(16) a) Willenbacher, J.; Altintas, O.; Trouillet, V.; Knofel, N.;
Monteiro, M. J.; Roesky, P. W.; Barner-Kowollik, C. Polymer Che-
mistry 2015, 6, 4358; b) Willenbacher, J.; Altintas, O.; Roesky, P. W.;
Barner-Kowollik, C. Macromol. Rapid Commun. 2014, 35, 45.
Corresponding Author
christopher.barner-kowollik@kit.edu; lehn@unistra.fr,
Author Contributions
#These authors contributed equally.
Notes
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a) Sanchez-Sanchez, A.; Arbe, A.; Colmenero, J.; Pomposo,
The authors declare no competing financial interests.
J. A. ACS Macro Lett. 2014, 3, 439. b) Sanchez-Sanchez, A.;Arbe, A.;
Kohlbrecher, J.; Colmenero, J.; Pomposo, J. A. Macromol. Rapid
Commun. 2015, 36, 1592.
ACKNOWLEDGMENT
L.G. thanks the A. v. Humboldt foundation for a post-
doctoral fellowship. J.M.-L. thanks the ERC (Advanced Re-
search Grant SUPRADAPT 290585) for support. C.B.-K.
acknowledges support from the Karlsruhe Institute of Tech-
nology (KIT) in the context of BIFTM and STN programs of
the Helmholtz association. The authors thank A. Eichdörfer
for X-ray chrystallography and P. A Levkin (KIT) for access to
DLS equipment.
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Jeong, J.; Lee, Y.-J.; Kim, B.; Kim, B.; Jung, K.-S.; Paik, H.-j.
Polym. Chem. 2015, 6, 3392.
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a) Mavila, S.; Diesendruck, C. E.; Linde, S.; Amir, L.;
Shikler, R.; Lemcoff, N. G. Angew. Chem. Int. Ed. 2013, 52, 5767;
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2014, 5, 4196.
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Guragain, S.; Bastakoti, B. P.; Malgras, V.; Nakashima, K.;
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McCarty, C. G. In Carbon–Nitrogen Double Bonds (1970);
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