Synlett p. 983 - 985 (1997)
Update date:2022-08-18
Topics:
Sugai, Takeshi
Hamada, Keiji
Akeboshi, Tomohiro
Ikeda, Hajime
Ohta, Hiromichi
Biocatalyst-mediated efficient preparation of highly enantiomerically enriched (R)-5-hexanolide (1) is described. The enantioselective reduction of 5-oxohexanoic acid with Yamadazyma farinosa IFO 10896 and the subseqent lipase-catalyzed kinetic resolution gave (R)-1 in 62% yield with 99.7% e.e.
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Doi:10.1016/j.cclet.2015.12.033
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(2006)Doi:10.1021/jacs.7b10033
(2017)Doi:10.1246/bcsj.55.3949
(1982)Doi:10.1016/j.molcata.2008.10.007
(2009)Doi:10.1039/c2ob06828a
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