Daphniphyllum Alkaloids. 15. Total Syntheses of (+/-)-Methyl Homodaphniphyllate and (+/-)-Daphnilactone A

DOI: 10.1021/jo00035a012

Source and publish data:

Journal of Organic Chemistry p. 2585 - 2594 (1992)

Update date:2022-08-24

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Authors:

Heathcock, Clayton H.

Ruggeri, Roger B.

McClure, Kim F.

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Article abstract of DOI:10.1021/jo00035a012

Biomimetic total syntheses of (+/-)-daphnilactone A (6) and (+/-)-methyl homodaphniphyllate (4) have been carried out.The syntheses began with the preparation of tricyclic lactone ether 18d, which was reduced to diol 19d with LiAlH4.Oxidation of 19d gave

Full text of DOI:10.1021/jo00035a012

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