Mechanism of Conjugate Additions of Dialkylcuprates to Bromonaphthoquinones

DOI: 10.1021/jo00012a002

Source and publish data:

Journal of Organic Chemistry p. 3759 - 3761 (1991)

Update date:2022-08-30

Topics:

Authors:

Wigal, Carl T.

Grunwell, John R.

Hershberger, James

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Article abstract of DOI:10.1021/jo00012a002

The correlation of bromonaphthoquinone redox potentials with reactivity toward dialkylcuprates reveals that the conjugate addition of Gilman reagents to bromojuglones proceeds via a single-electron-transfer mechanism.

Full text of DOI:10.1021/jo00012a002

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