Manganese Porphyrins Supported on Montmorillonite as Hydrocarbon Mono-oxygenation Catalysts: Particular Efficacy for Linear Alkane Hydroxylation

DOI: 10.1039/c39900001365

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1365 - 1367 (1990)

Update date:2022-08-11

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Authors:

Barloy, Laurent

Battioni, Pierrette

Mansuy, Daniel

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Article abstract of DOI:10.1039/c39900001365

A supported Mn-porphyrin catalyst has been prepared by immobilisation of the tetracationic Mn Cl⁴⁺ on montmorillonite, and is found to be efficient for alkene epoxidation and alkane hydroxylation by PhIO, with a higher ability to oxidize alkanes, and in particular short linear alkanes, than corresponding homogeneous or silica-supported Mn-porphyrin catalysts.

Full text of DOI:10.1039/c39900001365

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